CCl4 will not give the white precipitate of AgCl on heating it with silver nitrate. This is because the chlorine atoms are covalently bonded to carbon in CCl4. To obtain the precipitate, it should be present in ionic form and for this, it is necessary to prepare the Lassaigne's extract of CCl4.
Arrange the following compounds in the increasing order of their reactivity when each of them is reacted with chloroethane / anhydrous AlCl₃.
Two statements, Assertion and Reason are given below. Choose the correct option.
Assertion: $ \text{n-propyl tert-butyl ether can be readily prepared in the laboratory by Williamson's synthesis.} $
Reason: The reaction occurs by $ S_N1 $ attack of Primary alkoxide on Tert-alkyl halide to give a good yield of the product, $ \text{n-propyl tert-butyl ether.} $
Identify the final product formed when Toluene undergoes a series of reactions with reagents given in the order:
(i) \( \text{Cl}_2 / \text{Sunlight} \)
(ii) \( \text{H}_2\text{O}/373 \, \text{K} \)
(iii) Acetophenone / \( \text{OH}^- \) at 293 K
4 statements are given below. Identify the incorrect statement:
(A) Phenol has lower \( pK_a \) value than \( \text{p} \)-cresol.
(B) 2-Chlorophenol is more acidic than phenol.
(C) Ortho and para nitrophenols can be separated by steam distillation since \( \text{p} \)-Nitrophenol is more steam volatile than \( o \)-Nitrophenol.
(D) Phenol on reaction with \( \text{Cr}_2\text{O}_7^{2-} / \text{H}^+ \) yields a conjugated diketone.
What inference do you draw about the behaviour of Ag+ and Cu2+ from these reactions?
SN1 reaction mechanism takes place by following three steps –
The SN2 reaction mechanism involves the nucleophilic substitution reaction of the leaving group (which generally consists of halide groups or other electron-withdrawing groups) with a nucleophile in a given organic compound.
The mechanism of an electrophilic aromatic substitution reaction contains three main components which are:
The electrophilic substitution reaction mechanism is composed of three steps, which will be discussed more below.