Question:

Why is molecularity applicable only for elementary reactions whereas order is applicable for elementary as well as complex reactions? 

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Molecularity applies only to elementary reactions, while order applies to the overall reaction, regardless of whether it is elementary or complex.
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Solution and Explanation

Molecularity refers to the number of reacting species involved in an elementary reaction and is a property of that specific step. It applies only to elementary reactions because these reactions occur in a single step and involve a fixed number of reacting molecules. On the other hand, the order of a reaction is determined experimentally and refers to the relationship between the concentration of reactants and the rate of the overall reaction, which can apply to both elementary and complex reactions.

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