Why is it necessary to use acetic acid and not sulphuric acid for acidification of sodium extract for testing sulphur by lead acetate test?
Solution and Explanation
Although the addition of sulphuric acid will precipitate lead sulphate, the addition of acetic acid will ensure a complete precipitation of sulphur in the form of lead sulphate due to common ion effect. Hence, it is necessary to use acetic acid for acidification of sodium extract for testing sulphur by lead acetate test.
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Questions Asked in CBSE Class XI exam
- Identify the substance oxidised, reduced, oxidising agent and reducing agent for each of the following reactions:
- \(2AgBr (s) + C_6H_6O_2(aq) \rightarrow 2Ag(s) + 2HBr (aq) + C_6H_4O_2(aq)\)
- \(HCHO(l) + 2[Ag (NH_3)_2] ^+ (aq) + 3OH^ - (aq) \rightarrow 2Ag(s) + HCOO ^- (aq) + 4NH_3(aq) + 2H_2O(l)\)
- \(HCHO (l) + 2Cu^{ 2+}(aq) + 5 OH^ - (aq) \rightarrow Cu_2O(s) + HCOO ^- (aq) + 3H_2O(l)\)
- \(N_2H_4(l) + 2H_2O_2(l) \rightarrow N_2(g) + 4H_2O(l)\)
- \(Pb(s) + PbO_2(s) + 2H_2SO_4(aq) \rightarrow 2PbSO_4(s) + 2H_2O(l)\)
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Figure 8.9 shows the strain-stress curve for a given material. What are (a) Young’s modulus and (b) approximate yield strength for this material?
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Two identical ball bearings in contact with each other and resting on a frictionless table are hit head-on by another ball bearing of the same mass moving initially with a speed V. If the collision is elastic, which of the following (Fig. 5.14) is a possible result after collision ?
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Concepts Used:
Organic Chemistry – Some Basic Principles and Techniques - Reaction Mechanism
SN1 Reaction Mechanism:
SN1 reaction mechanism takes place by following three steps –
- Formation of carbocation
- Attack of nucleophile
- Deprotonation
SN2 Reaction Mechanism:
The SN2 reaction mechanism involves the nucleophilic substitution reaction of the leaving group (which generally consists of halide groups or other electron-withdrawing groups) with a nucleophile in a given organic compound.
Electrophilic Aromatic Substitution Reaction Mechanism:
The mechanism of an electrophilic aromatic substitution reaction contains three main components which are:
- A new sigma bond from C=C is formed during the reaction in the arene nucleophile.
- Due to the breaking of the C-H sigma bond, a proton is removed.
- The C=C bond is reformed and it restores the aromaticity of the compound.
Electrophilic Substitution Reaction Mechanism:
The electrophilic substitution reaction mechanism is composed of three steps, which will be discussed more below.
- Electrophile Generation
- Carbocation Formation
- Proton Removal