A shape tiles the plane if copies meet edge-to-edge with interior angles around every vertex summing to $360^\circ$.
- Circle: cannot tile because curved boundaries leave gaps unless stretched/overlapped. No.
- Regular octagon: interior angle $=135^\circ$; $360/135=2.666\ldots$ is not an integer, so identical regular octagons alone cannot fill the plane (they need squares). No.
- Regular pentagon: interior angle $=108^\circ$; $360/108=3.\overline{3}$ not an integer; identical regular pentagons cannot tile the plane. No.
- Rhombus (any parallelogram with equal sides): opposite angles are equal and adjacent angles sum to $180^\circ$; two copies meet to make $360^\circ$ around each vertex via translations. All parallelograms, hence rhombi, tile the plane. Yes.
\[
\boxed{\text{Rhombus tiles the plane}}
\]