Question:

Which one of the following pairs will show positive deviation from Raoult's Law?

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Positive deviation occurs when solute-solvent interactions are weaker than self-interactions, increasing vapor pressure.
Updated On: Dec 26, 2024
  • Water - HCl
  • Benzene - Methanol
  • Water - $HNO_3$
  • Acetone - Chloroform
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The Correct Option is B

Solution and Explanation

Benzene and methanol show positive deviation from Raoult's law because their solute-solvent interactions are weaker than their individual self-interactions, resulting in a higher vapour pressure than expected.
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