Step 1: Understand physical adsorption characteristics. - Physical adsorption is non-specific in nature.
- Enthalpy of adsorption is low (typically 20–40 kJ/mol).
- It forms multilayers especially under high pressure.
- However, it decreases with increase in temperature, since it is an exothermic process (Le Chatelier’s principle).
Step 2: Identify the incorrect statement. Option (3) says physical adsorption increases with temperature, which contradicts the above point. Hence, it is the incorrect statement.
List-I (Sol) | List-II (Method of preparation) |
---|---|
A) \( \text{As}_2\text{S}_3 \) | I) Bredig's arc method |
B) \( \text{Au} \) | II) Oxidation |
C) \( \text{S} \) | III) Hydrolysis |
D) \( \text{Fe(OH)}_3 \) | IV) Double decomposition |