Question:

Which one of the following has an optical isomer ? (en = ethylenediamine)

Updated On: Jul 2, 2022
  • $\left[Zn\left(en\right)\left(NH_{3}\right)_{2}\right]^{2+}$
  • $\left[Co\left(en\right)_{3}\right]^{3+}$
  • $\left[Co\left(H_{2}O\right)_{4}\left(en\right)\right]^{3+}$
  • $\left[Zn\left(en\right)_{2}\right]^{2+}$
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The Correct Option is B

Solution and Explanation

Only option (2) is having non-super imposable mirror image & hence one optical isomer.
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Concepts Used:

Coordination Compounds

A coordination compound holds a central metal atom or ion surrounded by various oppositely charged ions or neutral molecules. These molecules or ions are re-bonded to the metal atom or ion by a coordinate bond.

Coordination entity:

A coordination entity composes of a central metal atom or ion bonded to a fixed number of ions or molecules.

Ligands:

A molecule, ion, or group which is bonded to the metal atom or ion in a complex or coordination compound by a coordinate bond is commonly called a ligand. It may be either neutral, positively, or negatively charged.