Question:

Which one of the following first row transition elements is expected to have the highest third ionization enthalpy?

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For transition elements, the ionization enthalpy increases across the period due to increased nuclear charge and stability of electronic configurations.
  • Iron (Z = 26)
  • Manganese (Z = 25)
  • Chromium (Z = 24)
  • Vanadium (Z = 23)
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The Correct Option is B

Solution and Explanation

The third ionization enthalpy of transition elements increases as we move across the period due to increasing nuclear charge. Manganese has a half-filled d-subshell configuration, making it relatively stable and requiring more energy to remove the third electron. Hence, Manganese (Z = 25) has the highest third ionization enthalpy.
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