Question:

Which one among the following compounds will most readily be dehydrated under acidic condition? 

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Acidic dehydration trend:
\[ 3^\circ > 2^\circ > 1^\circ \]
More stable carbocation \( \Rightarrow \) faster elimination.
Updated On: Mar 2, 2026
  • Option a
  • Option b
  • Option c
  • Option d
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The Correct Option is D

Solution and Explanation

Concept:
Ease of dehydration depends on:
  • Stability of carbocation formed
  • Tertiary > Secondary > Primary
Step 1: Evaluate options
  • Primary alcohol (A): difficult dehydration
  • Alpha or beta hydroxy ketones: less favorable
  • Tertiary alcohol (D): forms stable 3° carbocation
Conclusion:
Tertiary alcohol dehydrates most easily.
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