Question:

Which of the following statement is not correct

Updated On: Apr 18, 2024
  • La(OH)3 is less basic than Lu(OH)3
  • ) In Lanthanide series ionic radius of Ln^+3 ions decreases
  • La is actually an element of transition series rather Lanthanide
  • Aomic radius of Zr and Hf are same because of Lanthanide contraction
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The Correct Option is A

Solution and Explanation

The correct option is(A): La(OH)3 is less basic than Lu(OH)3. La(OH)3 exhibits greater basicity compared to Lu(OH)3. In the lanthanide series, the basicity of hydroxides diminishes as the ionic radius decreases.
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Concepts Used:

Lanthanoids

Lanthanoids are at the top of these two-row, while actinoids are at the bottom row.

Properties of Lanthanoids

Lanthanoids are inclusive of 14 elements, with atomic numbers 58-71:

  • Cerium - Xe 4f1 5d1 6s2
  • Praseodymium - Xe 4f3 6s2
  • Neodymium - Xe 4f4 6s2
  • Promethium - Xe 4f5 6s2
  • Samarium - Xe 4f6 6s2
  • Europium - Xe 4f7 6s2
  • Gadolinium - Xe 4f7 5d1 6s2
  • Terbium - Xe 4f9 6s2
  • Dysprosium - Xe 4f10 6s2
  • Holmium - Xe 4f11 6s2
  • Erbium - Xe 4f12 6s2
  • Thulium - Xe 4f13 6s2
  • Ytterbium - Xe 4f14 6s2
  • Lutetium - Xe 4f14 5d1 6s2

These elements are also called rare earth elements. They are found naturally on the earth, and they're all radioactively stable except promethium, which is radioactive. A trend is one of the interesting properties of the lanthanoid elements, called lanthanide contraction.