Question:

Which of the following statement about hydrogen is incorrect ?

Updated On: July 22, 2025
  • Hydrogen never acts as cation in ionic salts
  • Hydronium ion, ${H_3O^+}$ exists freely in solution
  • Dihydrogen does not act as a reducing agent
  • Hydrogen has three isotopes of which tritium is the most common
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The Correct Option is D

Solution and Explanation

Hydrogen and its Reactions 

Hydrogen can exist as a hydride \({(H^{-})}\) in ionic salts.

The most abundant form of hydrogen is protium, which consists of a single proton and electron.

Dihydrogen (\({H_2(g)}\)) has the ability to reduce some metal ions in aqueous solutions and oxides of metals that are less active than iron into the corresponding metals. This reduction process can be shown as:

\({H_2(g) + Pd^{2+} (aq) \rightarrow Pd(s) + 2 H^{+} (aq)}\)

This reaction shows how dihydrogen reduces palladium ions (\({Pd^{2+}}\)) into solid palladium metal (\({Pd(s)}\)), with the formation of hydrogen ions (\({H^{+}}\)) in the process.

Another example of reduction is when dihydrogen reacts with metal oxides:

\({yH_2(g) + M_x O_y(s) \rightarrow xM(s) + yH_2O(\ell)}\)

In this reaction, dihydrogen reduces the metal oxide (\({M_x O_y}\)) to produce the metal (\({M(s)}\)) and water (\({H_2O(\ell)}\)).

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Concepts Used:

Bohr's Model of Hydrogen Atom

Niels Bohr introduced the atomic Hydrogen model in 1913. He described it as a positively charged nucleus, comprised of protons and neutrons, surrounded by a negatively charged electron cloud. In the model, electrons orbit the nucleus in atomic shells. The atom is held together by electrostatic forces between the positive nucleus and negative surroundings.

Read More: Bohr's Model of Hydrogen Atom

Bohr's Theory of Hydrogen Atom and Hydrogen-like Atoms

A hydrogen-like atom consists of a tiny positively-charged nucleus and an electron revolving around the nucleus in a stable circular orbit. 

Bohr's Radius: 

If 'e,' 'm,' and 'v' be the charge, mass, and velocity of the electron respectively, 'r' be the radius of the orbit, and Z be the atomic number, the equation for the radii of the permitted orbits is given by r = n2 xr1, where 'n' is the principal quantum number, and r1 is the least allowed radius for a hydrogen atom, known as Bohr's radius having a value of 0.53 Å. 

Limitations of the Bohr Model

The Bohr Model was an important step in the development of atomic theory. However, it has several limitations.

  1. Bohr’s model of the atom failed to explain the Zeeman Effect (effect of magnetic field on the spectra of atoms).
  2. It failed to explain the Stark effect (effect of electric field on the spectra of atoms).
  3. The spectra obtained from larger atoms weren’t explained.
  4. It violates the Heisenberg Uncertainty Principle.