In thermodynamics, properties of a system are classified into two categories: extensive and intensive properties. An extensive property depends on the size or extent of the system, while an intensive property does not. Examples of extensive properties include mass, volume, and total energy, whereas examples of intensive properties include pressure, temperature, and density.
Given the options: Pressure, Volume, Density, Temperature, we need to identify which is an extensive property.
Thus, the correct answer is: Volume, as it is the extensive property of the thermodynamic system.