Unsaturated hydrocarbons are those that contain one or more double or triple bonds between carbon atoms. These compounds do not have the maximum possible number of hydrogen atoms.
Butane (C₄H₁₀) is a saturated hydrocarbon with only single bonds between carbon atoms.
Butyne (C₄H₆) is an unsaturated hydrocarbon as it contains a triple bond between carbon atoms.
Isobutane (C₄H₁₀) is a saturated hydrocarbon, similar to butane.
Cyclobutane (C₄H₈) is a saturated hydrocarbon, despite having a ring structure, as all carbon-carbon bonds are single bonds.
Thus, the correct answer is Butyne, which is an unsaturated hydrocarbon due to the presence of a triple bond.
The correct option is (B): Butyne