Nitroglycerin, a vasodilator used to treat angina, is synthesized through the nitration of glycerol. Glycerol, a triol, reacts with nitric acid in the presence of sulfuric acid to form glyceryl trinitrate (nitroglycerin). Glycol, glucose, and glucitol are not suitable precursors for this reaction due to their different chemical structures and functional groups.
Thus, the correct answer is Glycerol.