In nucleophilic substitution reactions, the reactivity depends on the nature of the leaving group. Chlorine in \( \text{C}_6\text{H}_5\text{Cl} \) is a good leaving group, making this compound most reactive towards nucleophilic substitution.
Step 2: Conclusion.
The compound \( \text{C}_6\text{H}_5\text{Cl} \) undergoes nucleophilic substitution most easily, corresponding to option (a).