Question:

Which among the following is paramagnetic?

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A species with one or more unpaired electrons is paramagnetic. 

Updated On: Jun 9, 2024
  • Cl2O
  • ClO2
  • Cl2O7
  • Cl2O6
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The Correct Option is B

Solution and Explanation

A species with one or more unpaired electrons is paramagnetic. 
No. of valence electrons in Cl2O = 7 x 2 + 6 = 20 (even) 
No. of valence electrons in ClO2 = 7 + 6 x 2 = 19 (odd) 
No. of valence electrons in Cl2O7 = 7 x 2 + 6 x 7 = 56 (even) 
No. of valence electrons in Cl2O6 = 7 x 2 + 6 x 6 = 50 (even)
Thus, ClO2 is expected to be paramagnetic.

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Concepts Used:

P-Block Elements

  • P block elements are those in which the last electron enters any of the three p-orbitals of their respective shells. Since a p-subshell has three degenerate p-orbitals each of which can accommodate two electrons, therefore in all there are six groups of p-block elements.
  • P block elements are shiny and usually a good conductor of electricity and heat as they have a tendency to lose an electron. You will find some amazing properties of elements in a P-block element like gallium. It’s a metal that can melt in the palm of your hand. Silicon is also one of the most important metalloids of the p-block group as it is an important component of glass.

P block elements consist of: