Which among the following is paramagnetic?
A species with one or more unpaired electrons is paramagnetic.
A species with one or more unpaired electrons is paramagnetic.
No. of valence electrons in Cl2O = 7 x 2 + 6 = 20 (even)
No. of valence electrons in ClO2 = 7 + 6 x 2 = 19 (odd)
No. of valence electrons in Cl2O7 = 7 x 2 + 6 x 7 = 56 (even)
No. of valence electrons in Cl2O6 = 7 x 2 + 6 x 6 = 50 (even)
Thus, ClO2 is expected to be paramagnetic.
Given below are two statements. 
In the light of the above statements, choose the correct answer from the options given below:
Given below are two statements:
Statement I: Nitrogen forms oxides with +1 to +5 oxidation states due to the formation of $\mathrm{p} \pi-\mathrm{p} \pi$ bond with oxygen.
Statement II: Nitrogen does not form halides with +5 oxidation state due to the absence of d-orbital in it.
In the light of the above statements, choose the correct answer from the options given below:
Given below are the pairs of group 13 elements showing their relation in terms of atomic radius. $(\mathrm{B}<\mathrm{Al}),(\mathrm{Al}<\mathrm{Ga}),(\mathrm{Ga}<\mathrm{In})$ and $(\mathrm{In}<\mathrm{Tl})$ Identify the elements present in the incorrect pair and in that pair find out the element (X) that has higher ionic radius $\left(\mathrm{M}^{3+}\right)$ than the other one. The atomic number of the element (X) is