Question:

When m-chlorobenzaldehyde is treated with 50% KOH solution, the product(s) obtained is (are) 

Updated On: Aug 24, 2024
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The Correct Option is B

Solution and Explanation

When m-chlorobenzaldehyde reacts with a 50% KOH solution, it results in the formation of potassium meta chloro benzoate and meta chloro benzyl alcohol as the products. 
It's important to note that in this reaction, there are no alpha hydrogen atoms present in m-chloro benzaldehyde. Consequently, the reaction follows a Cannizzaro reaction mechanism, where one molecule undergoes oxidation to form meta chloro benzoic acid, while another molecule undergoes reduction to produce meta chloro benzyl alcohol.
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Concepts Used:

Aldehydes, Ketones and Carboxylic Acids - Chemical Reactions

Chemical Reactions of Aldehydes and Ketones:

Nucleophilic Addition Reactions
Nucleophilic Addition Reactions
Tollens’ test
Tollens’ Test
Fehling’s test
Fehling’s Test
Aldol condensation
Aldol Condensation
  • Cross aldol condensation
Cross aldol condensation
Cross Aldol Condensation
Cannizzaro reaction
Cannizzaro Reaction
Electrophilic Substitution Reaction
Electrophilic Substitution Reaction

Read Also: Aldehydes, Ketones, and Carboxylic Acids

Fischer Esterification
Fischer Esterification
Decarboxylation
Decarboxylation
Halogenation
Halogenation

Read More: Chemistry Named Reactions