Step 1: Understand the relationship between pH and pOH
For a strong base like \( \text{NaOH} \), the concentration of \( \text{OH}^- \) ions is equal to the concentration of the base. The pOH is given by:
\[
\text{pOH} = -\log[\text{OH}^-]
\]
The pH and pOH are related by:
\[
\text{pH} + \text{pOH} = 14
\]
Step 2: Calculate the pOH
Given:
- Concentration of \( \text{NaOH} = 0.001 \, \text{M} \),
- The concentration of \( \text{OH}^- \) ions is equal to the concentration of \( \text{NaOH} \), so \( [\text{OH}^-] = 0.001 \, \text{M} \).
Now, calculate the pOH:
\[
\text{pOH} = -\log(0.001) = 3
\]
Step 3: Calculate the pH
Now, use the relationship \( \text{pH} + \text{pOH} = 14 \):
\[
\text{pH} = 14 - 3 = 11
\]
Answer: Therefore, the pH of the \( 0.001 \, \text{M} \) solution of \( \text{NaOH} \) is \( 11 \). So, the correct answer is option (1).