What is the most likely configuration of the cobalt d-electrons for the species, $[CoCl_6]^{3-}$ and $[Co(NO_2)_6]^{3-}$?
- $[CoCl_6]^{3-}$ : low spin; $[Co(NO_2)_6]^{3-}$ : low spin
- $[CoCl_6]^{3-}$ : high spin; $[Co(NO_2)_6]^{3-}$ : low spin
- $[CoCl_6]^{3-}$ : low spin; $[Co(NO_2)_6]^{3-}$ : high spin
- $[CoCl_6]^{3-}$ : high spin; $[Co(NO_2)_6]^{3-}$ : high spin
The Correct Option is B
Solution and Explanation
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Concepts Used:
Coordination Compounds
A coordination compound holds a central metal atom or ion surrounded by various oppositely charged ions or neutral molecules. These molecules or ions are re-bonded to the metal atom or ion by a coordinate bond.
Coordination entity:
A coordination entity composes of a central metal atom or ion bonded to a fixed number of ions or molecules.
Ligands:
A molecule, ion, or group which is bonded to the metal atom or ion in a complex or coordination compound by a coordinate bond is commonly called a ligand. It may be either neutral, positively, or negatively charged.