Question:

What is the maximum absorption ($\lambda_{max}$) for a homo-annular conjugated diene according to the Woodward-Fieser Rules?

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Homo-annular diene → Woodward-Fieser $\lambda_{max}$ ≈ 253 nm.
Updated On: May 22, 2025
  • 253 nm
  • 217 nm
  • 5 nm
  • 215 nm
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The Correct Option is A

Solution and Explanation

According to Woodward-Fieser Rules, the $\lambda_{max}$ for a homo-annular diene (conjugated double bonds within the same ring) is around 253 nm. Substituents and auxochromes can further shift this value.
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