Question:

What is the difference between distillation, distillation under reduced pressure and steam distillation?

Updated On: Nov 16, 2023
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Solution and Explanation

The differences among distillation, distillation under reduced pressure, 

and steam distillation are given in the following table.

 DistillationDistillation under reduced pressureSteam distillation
1It is used for the purification of compounds that are associated with non-volatile impurities or those liquids, which do not decompose on boiling. In other words, distillation is used to separate volatile liquids from non-volatile impurities or a mixture of those liquids that have sufficient difference in boiling points.This method is used to purify a liquid that tends to decompose on boiling. Under the conditions of reduced pressure, the liquid will boil at a low temperature than its boiling point and will, therefore, not decompose.y a liquid that tends to decompose on boiling. Under the conditions of reduced pressure, the liquid will boil at a low temperature than its boiling point and will, therefore, not decompose. It is used to purify an organic compound, which is steam volatile and immiscible in water. On passing steam, the compound gets heated up and the steam gets condensed to water. After some time, the mixture of water and liquid starts to boil and passes through the condenser. This condensed mixture of water and liquid is then separated by using a separating funnel.
2Mixture of petrol and kerosene is separated by this method.Glycerol is purified by this method. It boils with decomposition at a temperature of 593 K. At a reduced pressure, it boils at 453 K without decomposition.A mixture of water and aniline is separated by steam distillation.
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Concepts Used:

Organic Chemistry – Some Basic Principles and Techniques - Reaction Mechanism

SN1 Reaction Mechanism:

SN1 reaction mechanism takes place by following three steps –

  • Formation of carbocation 
  • Attack of nucleophile 
  • Deprotonation 

SN2 Reaction Mechanism:

The SN2 reaction mechanism involves the nucleophilic substitution reaction of the leaving group (which generally consists of halide groups or other electron-withdrawing groups) with a nucleophile in a given organic compound.

Electrophilic Aromatic Substitution Reaction Mechanism:

The mechanism of an electrophilic aromatic substitution reaction contains three main components which are:

  1. A new sigma bond from C=C is formed during the reaction in the arene nucleophile.
  2. Due to the breaking of the C-H sigma bond, a proton is removed.
  3. The C=C bond is reformed and it restores the aromaticity of the compound.

Electrophilic Substitution Reaction Mechanism:

The electrophilic substitution reaction mechanism is composed of three steps, which will be discussed more below.

  • Electrophile Generation
  • Carbocation Formation
  • Proton Removal