Step 1: Definition of $Q$-value.
The $Q$-value of a nuclear reaction is the difference between the total binding energy of products and reactants:
\[
Q = (B.E._{products} - B.E._{reactants})
\]
If $Q>0$, the reaction is exothermic; if $Q<0$, it is endothermic.
Step 2: Binding energy of reactants.
Deuterium (${}^2H$) has 2 nucleons and B.E. per nucleon $= 1.25 \, \text{MeV}$.
\[
B.E._{D} = 2 \times 1.25 = 2.5 \, \text{MeV}
\]
Since two deuterium nuclei are involved:
\[
B.E._{reactants} = 2 \times 2.5 = 5.0 \, \text{MeV}
\]
Step 3: Binding energy of product helium.
Helium-4 has 4 nucleons and B.E. per nucleon $= 7.2 \, \text{MeV}$.
\[
B.E._{He} = 4 \times 7.2 = 28.8 \, \text{MeV}
\]
So,
\[
B.E._{products} = 28.8 \, \text{MeV}
\]
Step 4: Calculate $Q$-value.
\[
Q = B.E._{products} - B.E._{reactants} = 28.8 - 5.0 = 23.8 \, \text{MeV}
\]
(approx $23.6 \, \text{MeV}$ considering significant figures).
Step 5: Nature of reaction.
Since $Q>0$, the reaction is exothermic (energy releasing).
Step 6: Mass defect.
Energy released $Q = \Delta m c^2$.
In atomic mass units ($1u = 931 \, \text{MeV}$),
\[
\Delta m = \frac{Q}{931} = \frac{23.8}{931} \approx 0.025 \, u
\]
Step 7: Conclusion.
- The reaction is exothermic.
- $Q$-value $\approx 23.6 \, \text{MeV}$.
- Mass defect $\Delta m \approx 0.025 u$.