Step 1: VSEPR Theory.
The VSEPR (Valence Shell Electron Pair Repulsion) model helps predict the geometry of molecules based on the repulsion between electron pairs. The shape of a molecule depends on the number of bonding pairs and lone pairs around the central atom.
Step 2: Analyzing \( \text{PCl}_4^+ \).
For the \( \text{PCl}_4^+ \) ion:
- The central atom is phosphorus (P).
- It is surrounded by 4 chlorine atoms, forming 4 bonding pairs of electrons.
- The charge on the ion is \( +1 \), which means there is one fewer electron than the neutral molecule, so there are no lone pairs on the phosphorus atom.
Therefore, with 4 bonding pairs and no lone pairs, the shape is tetrahedral according to VSEPR theory.
Step 3: Conclusion.
Thus, the correct shape of the \( \text{PCl}_4^+ \) ion is tetrahedral, corresponding to option (1).
What is the empirical formula of a compound containing 40% sulfur and 60% oxygen by mass?
Match the LIST-I with LIST-II.
Choose the correct answer from the options given below :
Which of the following molecules(s) show/s paramagnetic behavior?
$\mathrm{O}_{2}$
$\mathrm{N}_{2}$
$\mathrm{F}_{2}$
$\mathrm{S}_{2}$
Given below are two statements:
Statement I : The N-N single bond is weaker and longer than that of P-P single bond
Statement II : Compounds of group 15 elements in +3 oxidation states readily undergo disproportionation reactions.
In the light of above statements, choose the correct answer from the options given below