Step 1: The maximum e.m.f. induced in the second coil is given by the formula \( \mathcal{E} = M \dfrac{dI}{dt} \), where \( M \) is the mutual inductance and \( \dfrac{dI}{dt} \) is the rate of change of current.
Step 2: The current is given by \( I = I_0 \sin(\omega t) \), so \( \dfrac{dI}{dt} = I_0 \omega \cos(\omega t) \). The maximum value occurs when \( \cos(\omega t) = 1 \).
Step 3: The maximum e.m.f. is:
\[
\mathcal{E_{\text{max}}} = M I_0 \omega = 0.005 \times 10 \times 100\pi = 2\pi \, \text{V}.
\]
Final Answer:
\[
\boxed{2\pi \, \text{V}}
\]