Question:

Three liquids of densities having the same value of surface tension $T$, rise to the same height in three identical capillaries. The angles of contact $\theta_{1}, \theta_{2}$ and $\theta_{3}$ obey-

Updated On: Apr 20, 2025
  • $\frac{\pi}{2} > \theta_1 > \theta_2 > \theta_3 \geq 0 $
  • $0 \leq \theta_1 < \theta_2 < \theta_3 < \frac{\pi}{2}$
  • $\frac{\pi}{2} < \theta_1 < \theta_2 < \theta_3 < \pi$
  • $\pi > \theta_1 > \theta_2 > \theta_3 > \frac{\pi}{2}$
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The Correct Option is B

Solution and Explanation

The given formula is:

\(h = \frac{2T \cos\theta_{c}}{r \rho g}\)

Where:

  • h is the height of the fluid column,
  • T is the surface tension,
  • r is the radius of the tube,
  • ρ is the density of the fluid,
  • g is the acceleration due to gravity,
  • θc is the contact angle between the fluid and the solid surface.

 

The equation shows that the height h is directly proportional to the cosine of the contact angle θc and the density of the fluid ρ.

The relationship can be expressed as:

\(\cos \theta_{c} \propto \rho\)

Which means, the cosine of the contact angle is directly proportional to the density of the fluid.

Comparing Densities and Contact Angles:

If ρ1 > ρ2 > ρ3, then the corresponding contact angles will follow the order:

\(\cos \theta_{c_1} > \cos \theta_{c_2} > \cos \theta_{c_3}\)

Thus, the angles will satisfy the relation:

\(0 \le \theta_{c_1} < \theta_{c_2} < \theta_{c_3} < \frac{\pi}{2}\)

In other words, as the density increases, the contact angle decreases.

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Concepts Used:

Surface Tension

The amount of energy required to increase the liquid's surface area by one unit area is known as surface tension. In other words, it is a property of the liquid surface to resist force.

Surface tension is defined as,

The ratio of the surface force F to the length L along which the force acts.

Mathematically, the surface tension formula can be expressed as follows:

T=F/L

Where,

  • F is the force per unit length
  • L is the length in which force act
  • T is the surface tension of the liquid

Read More: Detergents and Surface Tension

Factors affecting surface tension:

  • Impurities: The surface tension decreases with the addition of impurities.
  • Surfactants: Adding surfactants in liquids lowers the tension of water making it interrupt aside or get susceptible.
  • Temperature: The surface tension of a liquid reduces as the temperature rises.

The Unit of Surface Tension:

The SI unit of Surface Tension is Newton per Meter or N/m.