Step 1: Understand the van't Hoff factor.
The van't Hoff factor (\( i \)) represents the number of particles a compound dissociates into in solution.
For ionic compounds, \( i \) depends on the degree of dissociation.
Step 2: Analyze the given compounds. 1. KCl:
Dissociates into \( K^+ \) and \(Cl^-\).
Total particles = 2. \( i = 2 \). 2. NaCl:
Dissociates into \( Na^+ \) and \( Cl^-\).
Total particles = 2. \( i = 2 \). 3. \( K_2SO_4 \):
Dissociates into \( 2K^+ \) and \( SO_4^{2} \).
Total particles = 3. \( i = 3 \).
Step 3: Determine the correct answer.
The van't Hoff factors for KCl, NaCl, and \( K_2SO_4 \) are 2, 2, and 3, respectively.

If the molar conductivity ($\Lambda_m$) of a 0.050 mol $L^{–1}$ solution of a monobasic weak acid is 90 S $cm^{2} mol^{–1}$, its extent (degree) of dissociation will be:
[Assume: $\Lambda^0$ = 349.6 S $cm^{2} mol^{–1}$ and $\Lambda^0_{\text{acid}}$ = 50.4 S$ cm^{2} mol^{–1}$]