Chromium (Cr) has an atomic number of 24, which means it has 24 electrons. The electron configuration of chromium is:
\[
\text{Cr: } 1s^2 \, 2s^2 \, 2p^6 \, 3s^2 \, 3p^6 \, 3d^5 \, 4s^1
\]
From this, we can see that the electrons in the outermost shell (the 4th shell) are \( 4s^1 \) and \( 3d^5 \). Therefore, chromium has 6 valence electrons, with one electron in the \( 4s \) orbital and five electrons in the \( 3d \) orbitals.