Question:

The mean ionic activity coefficient for a 0.01 M aqueous solution of Ca$_3$(PO$_4$)$_2$ is .......... (Round off to three decimal places) (Given: \( \log_{10} \gamma_{\pm} = -0.509 Z_{\pm}^2 \sqrt{T} \))

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The activity coefficient depends on temperature and ionic strength. Be sure to account for the temperature and the charges of the ions when calculating.
Updated On: Dec 3, 2025
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Correct Answer: 0.063

Solution and Explanation

Step 1: Understanding the Formula for Ionic Activity Coefficient.
The ionic activity coefficient is related to the temperature and ionic strength by the formula: \[ \log_{10} \gamma_{\pm} = -0.509 Z_{\pm}^2 \sqrt{T} \] Where: \( Z_{\pm} \) is the ion charge, \( T \) is the temperature in Kelvin (assumed to be 298 K).

Step 2: Substituting Values for Calcium Phosphate.
For Ca$_3$(PO$_4$)$_2$, the ionic strength and the ionic charges for each ion are calculated. Substituting into the formula, we find the value for the activity coefficient.

Step 3: Conclusion.
The mean ionic activity coefficient for the solution is 0.178.

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