Step 1: Composition of Ordinary Portland Cement
\begin{itemize}
\item The primary components of Ordinary Portland Cement (OPC) are:
\[
\text{CaO} \approx 60\%, \quad
\text{SiO}_2 \approx 20\%, \quad
\text{Al}_2\text{O}_3 \approx 6\%, \quad
\text{Fe}_2\text{O}_3 \approx 3\%.
\]
\end{itemize}
Step 2: Determining the Major Components
\begin{itemize}
\item Among these, \(\text{CaO}\) (lime) and \(\text{SiO}_2\) (silica) are the most abundant.
\item Hence, from the given options, the pair of major components is \(\text{SiO}_2\) and \(\text{CaO}\).
\end{itemize}
Hence, the correct answer is \(\text{SiO}_2, \text{CaO}\).