Question:

The IUPAC name of the coordination compound Hg[Co(SCN)\(_4\)] is

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IUPAC names of coordination compounds depend on the oxidation state of the central metal and the nature of the ligands (e.g., S-cobaltate).
Updated On: Mar 7, 2025
  • Mercury (I) tetrathiocyanato-S-cobaltate (III)
  • Mercury (II) tetrathiocyanato-S-cobaltate (II)
  • Mercury (I) tetrathiocyanato-S-cobaltate (IV)
  • Mercury (II) tetraisocyanato-S-cobaltate (III)
  • Mercury (I) tetraisocyanato-N-cobaltate (III)
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The Correct Option is B

Solution and Explanation

Step 1: The correct IUPAC name reflects the oxidation state of mercury (II) and the coordination of four thiocyanate ions. 
Thus, the correct name is Mercury (II) tetrathiocyanato-S-cobaltate (II).

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