Step 1: Understanding the Rule
The statement describes the relationship between the valence of a flocculating ion and its ability to cause precipitation of a colloid. This is a well
known rule in colloid chemistry.
Step 2: Analyzing the Options
Hund's rule: This rule is related to the filling of electron orbitals in atoms, not colloid chemistry.
Pauling rule: This rule is related to the prediction of crystal structures, not colloid chemistry.
Henry's rule: This rule is related to the solubility of gases in liquids, not colloid chemistry.
Hardy—Schulze rule: This rule states that the greater the valence of the flocculating ion, the greater its power to cause precipitation of a colloid.
Step 3: Matching with the Options
The correct rule is the Hardy—Schulze rule, which corresponds to option (D).
Final Answer: The correct rule is (D) Hardy—Schulze rule.