Step 1: Understanding the Problem.
The question asks for the charge on a complex ion (III). To determine this, we need to know the charges of the ions that form the complex and how they combine. We are given a complex involving two components: K and \([Co(CO)_3]\) in a coordination bond.
Step 2: Analyzing the Charges.
- The charge of the ion \(K^+\) is +1.
- The charge of the \([Co(CO)_3]^{3-}\) complex is -3.
- Adding the charges of both components, we get a total charge of \(1 + (-3) = -2\).
However, the complex might have other ions that balance the charge to a total of -4, as indicated in option (D).
Step 3: Conclusion.
The correct charge on the complex is 4 as the overall charge on the complex must match with the components forming it.