Step 1: Understanding the Concept:
The question asks about the chemical precursor used in the industrial synthesis of chloroform (CHCl\(_3\)).
Step 2: Detailed Explanation:
Chloroform is produced industrially by the chlorination of methane. The reaction involves heating a mixture of chlorine and methane gas. This process is a free-radical substitution reaction and produces a mixture of chlorinated methanes (chloromethane, dichloromethane, chloroform, and carbon tetrachloride), which are then separated by distillation. The primary starting gas is Methane (CH\(_4\)).
\[ \text{CH}_4 + \text{Cl}_2 \rightarrow \text{CH}_3\text{Cl} + \text{HCl} \]
\[ \text{CH}_3\text{Cl} + \text{Cl}_2 \rightarrow \text{CH}_2\text{Cl}_2 + \text{HCl} \]
\[ \text{CH}_2\text{Cl}_2 + \text{Cl}_2 \rightarrow \text{CHCl}_3 \text{ (Chloroform)} + \text{HCl} \]
Step 3: Final Answer:
Methane is the gas used to make chloroform.