Step 1: Identify the anode reaction.
At the anode of a fuel cell, the fuel (in this case, methanol) undergoes oxidation. In the case of methanol fuel cells, methanol is oxidized to carbon dioxide, releasing electrons and protons.
Step 2: Conclusion.
Thus, the correct reaction at the anode is:
\[
\text{CH}_3\text{OH} \rightarrow \text{CO}_2 + 8\text{H}^+ + 8e^-
\]