Step 1: The de Broglie wavelength \( \lambda \) is given by the formula: \[ \lambda = \frac{h}{mv}, \] where \( h \) is Planck's constant, \( m \) is the mass of the particle, and \( v \) is the velocity.
Step 2: Since the de Broglie wavelength of the proton and the \( \alpha \)-particle are equal, we set their wavelengths equal: \[ \frac{h}{m_{{p}} v_{{p}}} = \frac{h}{m_{\alpha} v_{\alpha}}. \] Simplifying this gives: \[ \frac{v_{{p}}}{v_{\alpha}} = \frac{m_{\alpha}}{m_{{p}}}. \]
Step 3: The mass of the \( \alpha \)-particle is approximately 4 times the mass of the proton (\( m_{\alpha} = 4m_{{p}} \)). Thus, the ratio of the velocities is: \[ \frac{v_{{p}}}{v_{\alpha}} = \frac{4}{1}. \]
Step 4: Therefore, the ratio of their velocities is \( 4 : 1 \). \[ \boxed{4 : 1}. \]
The following orbital energies (\(E\)) are compared. Identify the correct sets
(I) E2(H) = E2(H)
(II) E3(H) = E3(He)
(III) E2s(H) < E2s(He)
(IV) E3s(He) < E3s(H)