Question:

The correct order of stability of carbocations, is:

Updated On: Jul 12, 2022
  • $1^{\circ} < 2^{\circ} < 3^{\circ} < \overset{+}{C} H_{3}$
  • $\overset{+}{C}H _{3} < 1^{\circ} < 2^{\circ} < 3^{\circ}$
  • $3^{\circ} < 2^{\circ} < 1^{\circ} < \overset{+}{C}H _{3}$
  • $2^{\circ} < 3^{\circ} < 1^{\circ} < \overset{+}{C}H _{3}$
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The Correct Option is B

Solution and Explanation

More the +I alkyl groups on electron deficient carbon, more stable will be the cabocation. Hence, $3^{\circ}$ carbocations are more stable. The correct order is $3^{\circ} > 2^{\circ} > 1^{\circ} > \overset{+}{C}H _{3}$
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Top Questions on Organic Chemistry- Some Basic Principles and Techniques

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Concepts Used:

Organic Chemistry – Some Basic Principles and Techniques - Reaction Mechanism

SN1 Reaction Mechanism:

SN1 reaction mechanism takes place by following three steps –

  • Formation of carbocation 
  • Attack of nucleophile 
  • Deprotonation 

SN2 Reaction Mechanism:

The SN2 reaction mechanism involves the nucleophilic substitution reaction of the leaving group (which generally consists of halide groups or other electron-withdrawing groups) with a nucleophile in a given organic compound.

Electrophilic Aromatic Substitution Reaction Mechanism:

The mechanism of an electrophilic aromatic substitution reaction contains three main components which are:

  1. A new sigma bond from C=C is formed during the reaction in the arene nucleophile.
  2. Due to the breaking of the C-H sigma bond, a proton is removed.
  3. The C=C bond is reformed and it restores the aromaticity of the compound.

Electrophilic Substitution Reaction Mechanism:

The electrophilic substitution reaction mechanism is composed of three steps, which will be discussed more below.

  • Electrophile Generation
  • Carbocation Formation
  • Proton Removal