Question:

The correct order of ionic radii of $Y ^{3+}, La ^{3+}$ $Eu ^{3+}$, and $Lu ^{3+}$ is : - Atomic nos. $Y =39,\, La =57,\, Eu =63,\, Lu =71$.

Updated On: Jul 13, 2024
  • $Lu^{3+ } < Eu^{3+} < La^{3+} < Y^{3+} $
  • $La^{3+ } < Eu^{3+} < Lu^{3+} < Y^{3+} $
  • $Y^{3+ } < La^{3+} < Eu^{3+} < Lu^{3+} $
  • $Y^{3+ } < Lu^{3+} < Eu^{3+} < La^{3+} $
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The Correct Option is D

Solution and Explanation

The correct order of ionic radii of $Y^{3+},La^{3+},Eu^{3+} $ and $ Lu^{3+}, $ is
$Y^{3+} < Lu^{3+} < Eu^{3+} < La^{3+} $ because Eu and Lu are the members of lanthanide series (so they show lanthanide contraction) and La is the representative element of all elements of such series and $Y^{3+} $ ion has lowei radii as comparison to $La^{3+} $ because it lies immediately above it in the periodic table.
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Concepts Used:

Lanthanoids

Lanthanoids are at the top of these two-row, while actinoids are at the bottom row.

Properties of Lanthanoids

Lanthanoids are inclusive of 14 elements, with atomic numbers 58-71:

  • Cerium - Xe 4f1 5d1 6s2
  • Praseodymium - Xe 4f3 6s2
  • Neodymium - Xe 4f4 6s2
  • Promethium - Xe 4f5 6s2
  • Samarium - Xe 4f6 6s2
  • Europium - Xe 4f7 6s2
  • Gadolinium - Xe 4f7 5d1 6s2
  • Terbium - Xe 4f9 6s2
  • Dysprosium - Xe 4f10 6s2
  • Holmium - Xe 4f11 6s2
  • Erbium - Xe 4f12 6s2
  • Thulium - Xe 4f13 6s2
  • Ytterbium - Xe 4f14 6s2
  • Lutetium - Xe 4f14 5d1 6s2

These elements are also called rare earth elements. They are found naturally on the earth, and they're all radioactively stable except promethium, which is radioactive. A trend is one of the interesting properties of the lanthanoid elements, called lanthanide contraction.