Question:

The conditions for the combination of atomic orbitals to form molecular orbitals are stated below. Mark the incorrect condition mentioned here.

Updated On: Jun 23, 2023
  • The combining atomic orbitals must have nearly same energy
  • The combining atomic orbitals must overlap to maximum extent
  • Combining atomic orbitals must have same symmetry about the molecular axis
  • Pi $(\pi)$ molecular orbitals are symmetrical around the bond axis
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The Correct Option is D

Solution and Explanation

Sigma molecular orbitals are symmetrical around the bond axis while pi molecular orbitals are not symmetrical.
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Concepts Used:

Molecular Orbital Theory

The Molecular Orbital Theory is a more sophisticated model of chemical bonding where new molecular orbitals are generated using a mathematical process called Linear Combination of Atomic Orbitals (LCAO).

Molecular Orbital theory is a chemical bonding theory that states that individual atoms combine together to form molecular orbitals. Due to this arrangement in MOT Theory, electrons associated with different nuclei can be found in different atomic orbitals. In molecular orbital theory, the electrons present in a molecule are not assigned to individual chemical bonds between the atoms. Rather, they are treated as moving under the influence of the atomic nuclei in the entire molecule

Molecular Orbital Theory
Molecular Orbital Theory