Step 1: Understanding Rosenmund reaction.
In the Rosenmund reduction, an acyl chloride is reduced to an aldehyde using palladium on barium sulfate (Pd / BaSO₄) as a catalyst.
Step 2: Conclusion.
Thus, the correct catalyst is option (B).
Final Answer:
\[
\boxed{\text{(B) Pd / BaSO₄}}
\]