Step 1: Identify the underlined prepositional phrase “in front of the store”, which indicates position or location.
Step 2: Check each option to see whether it can logically replace the given preposition:
Across the store – indicates location relative to the store and is grammatically acceptable.
Next to the store – correctly shows position beside the store.
At the back of the store – also indicates a valid location.
On the store – is incorrect because a car cannot be parked on a store.
Step 3: Therefore, the unsuitable preposition is “on”.