The formula for pyrrhotite is FeS, which contains one atom of iron (Fe) and one atom of sulfur (S).
To calculate the atom percent of iron (Fe), we need the molar masses of Fe and S:
Using the formula FeS, we calculate the number of moles of Fe and S:
The formula for calculating the atom percent of Fe is:
\[ \text{Atom percent of Fe} = \frac{0.77}{0.77 + 1} \times 100 = 43.51\% \]
Thus, the atom percent of Fe in pyrrhotite is 43.51%.