Step 1: Relativistic Kinetic Energy Formula.
The relativistic kinetic energy is given by:
\[
K.E. = (\gamma - 1) m c^2
\]
where \( \gamma = \frac{1}{\sqrt{1 - (v/c)^2}} \), \( m \) is the rest mass, and \( c \) is the speed of light.
Step 2: Calculating \( \gamma \) at \( v = c/3 \) and \( v = 2c/3 \).
For \( v = c/3 \),
\[
\gamma_1 = \frac{1}{\sqrt{1 - (1/3)^2}} = \frac{1}{\sqrt{8/9}} = \frac{3}{\sqrt{8}}
\]
For \( v = 2c/3 \),
\[
\gamma_2 = \frac{1}{\sqrt{1 - (2/3)^2}} = \frac{1}{\sqrt{5/9}} = \frac{3}{\sqrt{5}}
\]
Step 3: Work done.
The work done is the difference in kinetic energy:
\[
W = (\gamma_2 - \gamma_1) m c^2 = \left( \frac{3}{\sqrt{5}} - \frac{3}{\sqrt{8}} \right) \times 0.511 \, \text{MeV}
\]
After evaluating the expression, we get \( W = 143.58 \, \text{keV} \).
Step 4: Conclusion.
Thus, the work done to increase the speed of the electron is 143.58 keV, so the correct answer is (B).