Question:

The alcohol having molecular formula $C_4H_9OH$, when shaken with a mixture of anhydrous $ZnCl_2$ and conc. $HCl$ gives an oily layer product after five minutes. The alcohol is

Updated On: Apr 15, 2024
  • $H_3C ? (CH_2)_3 ? OH$
  • $(CH_3)_2CH ? CH_2OH$
  • $(CH_3)_3C ? OH$
  • $H_3C ? CH(OH) CH_2 ? CH_3$
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The Correct Option is D

Solution and Explanation

Secondary alcohol, on reaction with anhydrous $ZnCl _{2}$ and conc. $HCl$ (Lucas reagent) gives an oily layer product after five minuts.
$H_{3}C -\underset{\overset{|}{OH}}{CH} - CH_{2}CH_{3} {->[{\text{Lucas reagent}}]}$ oily layer
product (turbidity) after 5 min.
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Concepts Used:

Alcohols

What is Alcohol?

Alcohol is a derivative of water (H2O) that has one, two, or more hydroxyl groups that are attached to a carbon atom of a hydrocarbon chain (an alkyl group). It is one of the most common organic compounds used in sweeteners, fragrances, and medicine. 

Read More: Types of Alcohol

Uses of Alcohol:

  • Ethanol is the alcohol used in alcoholic drinks. It can be used as an industrial methylated spirit where methanol is used very little in quantity as it can be dangerous.
  • It is used as fuel to produce carbon dioxide and water by the process of fermentation. Whereas methanol burns carbon dioxide and water to facilitate combustion.
  • Alcohol is an organic compound used as a solvent that is insoluble in water.
  • It can be used to lower the level of sugar.
  • Alcohol is used as a preservative in laboratories.