Question:

Specific Conductance of 0.1 M HNO3 is 6.3 x 10-2 ohm -1 cm-1. The molar conductance of the solution is

Updated On: Apr 8, 2025
  • 6300 ohm-1 cm2 mol-1
  • 630 ohm-1 cm2 mol-1
  • 63.0 ohm-1 cm2 mol-1
  • 315 ohm-1 cm2 mol-1
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The Correct Option is A

Approach Solution - 1

Molar Conductance (Λm) is given by:
Λm = κ × 1000 / C

where,
κ = specific conductance = \(6.3 \times 10^{-2}\) ohm-1 cm-1
C = concentration = 0.1 mol/L

Substituting the values:
Λm = \( \frac{6.3 \times 10^{-2} \times 1000}{0.1} = 630 \) ohm-1 cm2 mol-1

Correct Answer: 630 ohm-1 cm2 mol-1

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Approach Solution -2

Given: 

  • Specific conductance \( \kappa = 6.3 \times 10^{-2} \, \text{ohm}^{-1} \, \text{cm}^{-1} \)
  • Concentration \( C = 0.1 \, \text{mol L}^{-1} \)

Formula:
Molar conductance \( \Lambda_m = \frac{\kappa \times 1000}{C} \)

Substitute the values:
$$ \Lambda_m = \frac{6.3 \times 10^{-2} \times 1000}{0.1} = \frac{63}{0.1} = 630 \, \text{ohm}^{-1} \, \text{cm}^2 \, \text{mol}^{-1} $$

Correct answer: 630 ohm-1 cm2 mol-1

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