Step 1: Use the relation for BCC crystal structure.
In a body-centered cubic (BCC) structure, the relation between the atomic radius \( r \) and the lattice parameter \( a \) is given by:
\[
a = \frac{4r}{\sqrt{3}}
\]
where \( r = 0.186 \, \text{nm} \) is the atomic radius.
Step 2: Calculate the lattice parameter.
Substituting the value of \( r \):
\[
a = \frac{4 \times 0.186}{\sqrt{3}} = 0.528 \, \text{nm}
\]
Step 3: Conclusion.
Thus, the lattice parameter of Na unit cell is 0.528 nm.