Question:

Schottky defect in a crystal is observed when

Updated On: Jul 28, 2022
  • an ion leaves its normal site and occupies an interstitial site
  • unequal number of cations and anions are missing from the lattice
  • density of the crystal is increased
  • equal number of cations and anions are missing from the lattice
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The Correct Option is D

Solution and Explanation

In Schottky defect, equal number of cations and anions are missing from the lattice. Due to this defect, density of crystal decreases.
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Concepts Used:

Imperfections in Solids

Any irregularity in the pattern of crystal arrangement in a solid lattice is called imperfection in solids. The occurrence of defects takes place when crystallization (the process of formation of crystals) occurs at a very fast or at an intermediate rate.

Basically, defects fall out in two forms:

  • Point Defect

When the irregularities exist from the ideal arrangement around a point or an atom in solids, the defect is known as a point defect. Types of point defects are:

  • Stoichiometric defects
  • Non-stoichiometric defects
  • Impurity defects
  • Line Defect

When the deviation from the ideal arrangement exists in the entire row of lattice points, the defect is called line defect.