$2 \text{ v}$

Step 4: Express velocity v in terms of kinetic energy
K.E.max = (1/2) m v² = hf
Step 5: Calculate K.E. for frequency 4.25f
Energy of photon at 4.25f: E = h × 4.25f = 4.25hf
Work function φ = 2hf (same as before)
Maximum kinetic energy at 4.25f:
K.E.max = 4.25hf − 2hf = 2.25hf
Step 6: Find the new maximum velocity v'
Let the new maximum velocity be v'. Then:
(1/2) m v'² = 2.25hf
Step 7: Relate v' to v
From Step 4, hf = (1/2) m v²
Divide the two equations:
(v'²) / (v²) = 2.25
=> v' / v = √2.25 = 1.5
Step 8: Conclusion
The maximum velocity of the photoelectrons when frequency is 4.25f is 1.5 times the velocity v.
Hence, the answer is 1.5 v.