Question:

$ PC{{l}_{5}} $ is possible but $ NC{{l}_{5}} $ does not exist

Updated On: Jul 28, 2022
  • in $ N,\,\,d- $ sub-shell is absent
  • ionization energy of $ N $ is very high
  • it does not like $ Cl $
  • none of the above
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The Correct Option is A

Solution and Explanation

Nitrogen cannot form pentahalides because it cannot expand its octet due to non-availability of $ d- $ orbitals.
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Concepts Used:

P-Block Elements

  • P block elements are those in which the last electron enters any of the three p-orbitals of their respective shells. Since a p-subshell has three degenerate p-orbitals each of which can accommodate two electrons, therefore in all there are six groups of p-block elements.
  • P block elements are shiny and usually a good conductor of electricity and heat as they have a tendency to lose an electron. You will find some amazing properties of elements in a P-block element like gallium. It’s a metal that can melt in the palm of your hand. Silicon is also one of the most important metalloids of the p-block group as it is an important component of glass.

P block elements consist of: