Step 1: Rainboots (P).
- Rainboots are hollow, large, and need uniform thickness.
- They are generally made by rotational molding, where powdered polymer is heated inside a rotating mold to form hollow objects.
\(\Rightarrow P-3\).
Step 2: Disposable plastic cups (Q).
- Plastic cups are thin-walled and shaped by heating thermoplastic sheets and pressing them into molds.
- This process is known as thermoforming.
\(\Rightarrow Q-4\).
Step 3: Soft drink bottles (R).
- Bottles are hollow objects manufactured by inflating hot polymer into a mold cavity.
- This is blow molding.
\(\Rightarrow R-1\).
Step 4: Flexible films (S).
- Polymer films are manufactured by squeezing molten polymer between heated rollers to form sheets.
- This is calendering.
\(\Rightarrow S-2\).
Step 5: Combine all matches.
\[
P-3,\; Q-4,\; R-1,\; S-2
\]
Final Answer:
\[
\boxed{\text{(B) P-3; Q-4; R-1; S-2}}
\]