Step 1: Recall the principles of each test.
- Thiobarbituric acid (TBA) test: Measures malondialdehyde (secondary oxidation) → Carbonyl content.
- Rancimat method: Accelerated oxidation → Induction time.
- Peroxide value: Primary oxidation product → Hydroperoxide content.
- Iodine value: Measures double bonds → Degree of unsaturation.
Step 2: Final Matching.
- P → 3
- Q → 1
- R → 4
- S → 2
Final Answer:
\[
\boxed{\text{(A) P-3, Q-1, R-4, S-2}}
\]